blast furnace in Port of Sagunt, Valencia, Spain]]A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. Blast refers to the combustion air being supplied above atmospheric pressure.
In a blast furnace, fuel (coke), ores, and flux (limestone) are continuously supplied through the top of the furnace, while a hot blast of (sometimes oxygen-enriched) air is blown into the lower section of the furnace through a series of pipes called tuyeres, so that the chemical reactions take place throughout the furnace as the material falls downward. The end products are usually molten metal and slag phases tapped from the bottom, and exiting from the top. The downward flow of the ore along with the flux in contact with an upflow of hot, carbon monoxide-rich combustion gases is a countercurrent exchange and chemical reaction process.
In contrast, air furnaces (such as reverberatory furnaces) are naturally aspirated, usually by the convection of hot gases in a Chimney-flue. According to this broad definition, bloomery for iron, for tin, and for lead would be classified as blast furnaces. However, the term has usually been limited to those used for smelting iron ore to produce pig iron, an intermediate material used in the production of commercial iron and steel, and the shaft furnaces used in combination with in base metals smelting.P J Wand, "Copper smelting at Electrolytic Refining and Smelting Company of Australia Ltd., Port Kembla, N.S.W.", in: Mining and Metallurgical Practices in Australasia: The Sir Maurice Mawby Memorial Volume, Ed J T Woodcock (The Australasian Institute of Mining and Metallurgy: Melbourne, 1980) 335–340.R J Sinclair, The Extractive Metallurgy of Lead (The Australasian Institute of Mining and Metallurgy: Melbourne, 2009), 9–12.
Blast furnaces are estimated to have been responsible for over 4% of global greenhouse gas emissions between 1900 and 2015, and are difficult to decarbonize.
Blast furnaces differ from bloomery and reverberatory furnaces in that in a blast furnace, flue gas is in direct contact with the ore and iron, allowing carbon monoxide to diffuse into the ore and reduce the iron oxide. The blast furnace operates as a countercurrent exchange process whereas a bloomery does not. Another difference is that bloomeries operate as a batch process whereas blast furnaces operate continuously for long periods. Continuous operation is also preferred because blast furnaces are difficult to start and stop. Also, the carbon in pig iron lowers the melting point below that of steel or pure iron; in contrast, iron does not melt in a bloomery.
Silica has to be removed from the pig iron. It reacts with calcium oxide (burned limestone) and forms silicates, which float to the surface of the molten pig iron as slag. Historically, iron was produced with charcoal to prevent sulfur contamination.
In a blast furnace, a downward-moving column of ore, flux, coke (or charcoal) and their reaction products must be sufficiently porous for the flue gas to pass through, upwards. To ensure this permeability the particle size of the coke or charcoal is of great relevance. Therefore, the coke must be strong enough so it will not be crushed by the weight of the material above it. Besides the physical strength of its particles, the coke must also be low in sulfur, phosphorus, and ash.
The main chemical reaction producing the molten iron is:
This reaction might be divided into multiple steps, with the first being that preheated air blown into the furnace reacts with the carbon in the form of coke to produce carbon monoxide and heat:
Hot carbon monoxide is the reducing agent for the iron ore and reacts with the iron oxide to produce molten iron and carbon dioxide. Depending on the temperature in the different parts of the furnace (warmest at the bottom) the iron is reduced in several steps. At the top, where the temperature usually is in the range between 200 °C and 700 °C, the iron oxide is partially reduced to iron(II,III) oxide, Fe3O4.
The temperatures 850 °C, further down in the furnace, the iron(II,III) is reduced further to iron(II) oxide:
Hot carbon dioxide, unreacted carbon monoxide, and nitrogen from the air pass up through the furnace as fresh feed material travels down into the reaction zone. As the material travels downward, the counter-current gases both preheat the feed charge and decompose the limestone to calcium oxide and carbon dioxide:
The calcium oxide formed by decomposition reacts with various acidic impurities in the iron (notably silica), to form a fayalite slag which is essentially calcium silicate, :
As the iron(II) oxide moves down to the area with higher temperatures, ranging up to 1200 °C degrees, it is reduced further to iron metal:
The carbon dioxide formed in this process is re-reduced to carbon monoxide by the coke:
The temperature-dependent equilibrium controlling the gas atmosphere in the furnace is called the Boudouard reaction:
The pig iron produced by the blast furnace has a relatively high carbon content of around 4–5% and usually contains too much sulphur, making it very brittle, and of limited immediate commercial use. Some pig iron is used to make cast iron. The majority of pig iron produced by blast furnaces undergoes further processing to reduce the carbon and sulphur content and produce various grades of steel used for construction materials, automobiles, ships and machinery. Desulphurisation usually takes place during the transport of the liquid steel to the steelworks. This is done by adding calcium oxide, which reacts with the iron sulfide contained in the pig iron to form calcium sulfide (called lime desulfurization). In a further process step, the so-called basic oxygen steelmaking, the carbon is oxidized by blowing oxygen onto the liquid pig iron to form crude steel.
Although cast iron farm tools and weapons were widespread in China by the 5th century BC, employing workforces of over 200 men in iron smelters from the 3rd century onward, the earliest blast furnaces constructed were attributed to the Han dynasty in the 1st century AD.Ebrey, p. 30. These early furnaces had clay walls and used phosphorus-containing minerals as a flux. Early iron in China, Korea, and Japan , Donald B. Wagner, March 1993 Chinese blast furnaces ranged from around two to ten meters in height, depending on the region. The largest ones were found in modern Sichuan and Guangdong, while the 'dwarf" blast furnaces were found in Dabieshan. In construction, they are both around the same level of technological sophistication.
The effectiveness of the Chinese human and horse powered blast furnaces was enhanced during this period by the engineer Du Shi (c. AD 31), who applied the power of to piston-bellows in forging cast iron. Early water-driven reciprocators for operating blast furnaces were built according to the structure of horse powered reciprocators that already existed. That is, the circular motion of the wheel, be it horse driven or water driven, was transferred by the combination of a belt drive, a crank-and-connecting-rod, other connecting rods, and various shafts, into the reciprocal motion necessary to operate push bellows.
The primary advantage of the early blast furnace was in large scale production and making iron implements more readily available to peasants. Cast iron is more brittle than wrought iron or steel, which required additional fining and then cementation or co-fusion to produce, but for menial activities such as farming it sufficed. By using the blast furnace, it was possible to produce larger quantities of tools such as ploughshares more efficiently than the bloomery. In areas where quality was important, such as warfare, wrought iron and steel were preferred. Nearly all Han period weapons are made of wrought iron or steel, with the exception of axe-heads, of which many are made of cast iron.
Blast furnaces were also later used to produce gunpowder weapons such as cast iron bomb shells and cast iron during the Song dynasty.
The technology required for blast furnaces may have either been transferred from China, or may have been an indigenous innovation. Al-Qazvini in the 13th century and other travellers subsequently noted an iron industry in the Alborz Mountains to the south of the Caspian Sea. This is close to the silk route, so that the use of technology derived from China is conceivable. Much later descriptions record blast furnaces about three metres high.Wagner 2008, 349–351. As the Varangian Rus' people from Scandinavia traded with the Caspian (using their Volga trade route), it is possible that the technology reached Sweden by this means.Wagner 2008, 354. The Vikings are known to have used double bellows, which greatly increases the volumetric flow of the blast.
The Caspian region may also have been the source for the design of the furnace at Ferriere, described by Filarete,Wagner 2008, 355. involving a water-powered bellows at Semogo in Valdidentro in northern Italy in 1226. In a two-stage process the molten iron was tapped twice a day into water, thereby granulating it.
Archaeologists are still discovering the extent of Cistercian technology.Woods, p. 36. At Laskill, an outstation of Rievaulx Abbey and the only medieval blast furnace so far identified in Great Britain, the slag produced was low in iron content.Woods, p. 37. Slag from other furnaces of the time contained a substantial concentration of iron, whereas Laskill is believed to have produced cast iron quite efficiently.David Derbyshire, 'Henry "Stamped Out Industrial Revolution"' , The Daily Telegraph (21 June 2002); cited by Woods. Its date is not yet clear, but it probably did not survive until Henry VIII's Dissolution of the Monasteries in the late 1530s, as an agreement (immediately after that) concerning the "smythes" with the Earl of Rutland in 1541 refers to blooms. Nevertheless, the means by which the blast furnace spread in medieval Europe has not finally been determined.
The direct ancestor of those used in France and England was in the Namur region, in what is now Wallonia (Belgium). From there, they spread first to the Pays de Bray on the eastern boundary of Normandy and from there to the Weald of Sussex, where the first furnace (called Queenstock) in Buxted was built in about 1491, followed by one at Newbridge in Ashdown Forest in 1496. They remained few in number until about 1530 but many were built in the following decades in the Weald, where the iron industry perhaps reached its peak about 1590. Most of the pig iron from these furnaces was taken to for the production of bar iron.
The first British furnaces outside the Weald appeared during the 1550s, and many were built in the remainder of that century and the following ones. The output of the industry probably peaked about 1620, and was followed by a slow decline until the early 18th century. This was apparently because it was more economic to import iron from Sweden and elsewhere than to make it in some more remote British locations. Charcoal that was economically available to the industry was probably being consumed as fast as the wood to make it grew.P. W. King, 'The production and consumption of iron in early modern England and Wales' Economic History Review LVIII(1), 1–33; G. Hammersley, 'The charcoal iron industry and its fuel 1540–1750' Economic History Review Ser. II, XXVI (1973), pp. 593–613.
The first blast furnace in Russia opened in 1637 near Tula and was called the Gorodishche Works. The blast furnace spread from there to central Russia and then finally to the Urals.
Coke iron was initially only used for foundry work, making pots and other cast iron goods. Foundry work was a minor branch of the industry, but Darby's son built a new furnace at nearby Horsehay, and began to supply the owners of with coke pig iron for the production of bar iron. Coke pig iron was by this time cheaper to produce than charcoal pig iron. The use of a coal-derived fuel in the iron industry was a key factor in the British Industrial Revolution.Hyde However, in many areas of the world charcoal was cheaper while coke was more expensive even after the Industrial Revolution: e. g., in the US charcoal-fueled iron production fell in share to about a half but still continued to increase in absolute terms until , while in João Monlevade in the Brazilian Highlands charcoal-fired blast furnaces were built as late as the 1930s and only phased out in 2000.
Darby's original blast furnace has been archaeologically excavated and can be seen in situ at Coalbrookdale, part of the Ironbridge Gorge Museums. Cast iron from the furnace was used to make for the world's first cast iron bridge in 1779. The Iron Bridge crosses the River Severn at Coalbrookdale and remains in use for pedestrians.
Hot blast enabled the use of raw anthracite coal, which was difficult to light, in the blast furnace. Anthracite was first tried successfully by George Crane at Ynyscedwyn Ironworks in south Wales in 1837.Hyde, p. 159. It was taken up in America by the Lehigh Crane Iron Company at Catasauqua, Pennsylvania, in 1839. Anthracite use declined when very high capacity blast furnaces requiring coke were built in the 1870s.
This is a great increase from the typical 18th-century furnaces, which averaged about per year. Variations of the blast furnace, such as the Swedish electric blast furnace, have been developed in countries which have no native coal resources.
According to Global Energy Monitor, the blast furnace is likely to become obsolete to meet climate change objectives of reducing carbon dioxide emission, but BHP disagrees. An alternative process involving direct reduced iron (DRI) is likely to succeed it, but this also needs to use a blast furnace to melt the iron and remove the gangue (impurities) unless the ore is very high quality.
OBFs are usually combined with top gas recycling. The problem with this, besides significant oxygen expenditures, is the uneven distribution of gas recycled from the top of the furnace to the middle, which collides with the hot gas from below. As of 2023, the technology is only practiced on the experimental level in Sweden, Japan and China.
The blast furnace used at the Nyrstar Port Pirie lead smelter differs from most other lead blast furnaces in that it has a double row of tuyeres rather than the single row normally used. The lower shaft of the furnace has a chair shape with the lower part of the shaft being narrower than the upper. The lower row of tuyeres being located in the narrow part of the shaft. This allows the upper part of the shaft to be wider than the standard.
Blast furnaces used in the ISP have a more intense operation than standard lead blast furnaces, with higher air blast rates per m2 of hearth area and a higher coke consumption.
Zinc production with the ISP is more expensive than with electrolytic zinc plants, so several smelters operating this technology have closed in recent years.R J Sinclair, The Extractive Metallurgy of Lead (The Australasian Institute of Mining and Metallurgy: Melbourne, 2009), 90. However, ISP furnaces have the advantage of being able to treat zinc concentrates containing higher levels of lead than can electrolytic zinc plants.
There are different ways in which the raw materials are charged into the blast furnace. Some blast furnaces use a "double bell" system where two "bells" are used to control the entry of raw material into the blast furnace. The purpose of the two bells is to minimize the loss of hot gases in the blast furnace. First, the raw materials are emptied into the upper or small bell which then opens to empty the charge into the large bell. The small bell then closes, to seal the blast furnace, while the large bell rotates to provide specific distribution of materials before dispensing the charge into the blast furnace.
The iron making blast furnace itself is built in the form of a tall structure, lined with refractory brick, and profiled to allow for expansion of the charged materials as they heat during their descent, and subsequent reduction in size as melting starts to occur. Coke, limestone flux, and iron ore (iron oxide) are charged into the top of the furnace in a precise filling order which helps control gas flow and the chemical reactions inside the furnace. Four "uptakes" allow the hot, dirty gas high in carbon monoxide content to exit the furnace throat, while "bleeder valves" protect the top of the furnace from sudden gas pressure surges. The coarse particles in the exhaust gas settle in the "dust catcher" and are dumped into a railroad car or truck for disposal, while the gas itself flows through a venturi scrubber and/or electrostatic precipitators and a gas cooler to reduce the temperature of the cleaned gas.
The "casthouse" at the bottom half of the furnace contains the bustle pipe (a large-diameter annular pipe to deliver heated air under pressure to the ) and the equipment for casting the liquid iron and slag. Once a "taphole" is drilled through the refractory clay plug, liquid iron and slag flow down a trough through a "skimmer" opening, separating the iron and slag. Modern, larger blast furnaces may have as many as four tapholes and two casthouses. Once the pig iron and slag has been tapped, the taphole is again plugged with refractory clay.
The tuyeres are used to implement a hot blast, which is used to increase the efficiency of the blast furnace. The hot blast is directed into the furnace through water-cooled copper nozzles called tuyeres near the base. The hot blast temperature can be from depending on the stove design and condition. The temperatures they deal with may be . Oil, tar, natural gas, powdered coal and oxygen can also be injected into the furnace at tuyere level to combine with the coke to release additional energy and increase the percentage of reducing gases present which is necessary to increase productivity.
The exhaust gasses of a blast furnace are generally cleaned in the dust collector – such as an separator, a baghouse, or an electrostatic precipitator. Each type of dust collector has strengths and weaknesses – some collect fine particles, some coarse particles, some collect electrically charged particles. Effective exhaust clearing relies on multiple stages of treatment. Waste heat is usually collected from the exhaust gases, for example by the use of a Cowper stove, a variety of heat exchanger.
Electric arc furnaces (EAF) are cited as an alternative steel production path which avoids the use of blast furnaces, however, depending on the characteristics of the steel product required the two furnace types are not always interchangeable. Furthermore, EAFs utilize steel scrap as a feedstock but estimates suggest that there will not be enough scrap available to meet future steel demand. Using hydrogen gas as a reductant to produce DRI (so called H2-DRI) from iron ore, which is then used as a feedstock for an EAF provides a technologically feasible, low emission alternative to blast furnaces. The H2-DRI EAF production route is in a fledgling state, with just one plant in operation.
ULCOS (Ultra Low Carbon Dioxide Steelmaking)http://www.ulcos.org was a European programme exploring processes to reduce blast furnace emissions by at least 50%. Technologies identified include carbon capture and storage (CCS) and alternative energy sources and reductants such as hydrogen, electricity and biomass.ICIT-Revue de Métallurgie, September and October issues, 2009
==Gallery==
History
China
Medieval Europe
Oldest European blast furnaces
Cistercian contributions
Origin and spread of early modern blast furnaces
Coke blast furnaces
Steam-powered blast
Hot blast
Modern applications of the blast furnace
Iron blast furnaces
Oxygen blast furnace
Blast furnaces in copper and lead smelting
Zinc blast furnaces
Manufacture of stone wool
Modern iron process
Environmental impact
Accessed 30 July 2021. Fuels and reductants such as plastic waste, biomass and hydrogen are being used by steelmakers as possible alternatives to fossil fuels, although cost and availability remain a challenge and deployment is limited.
Carbon capture, utilisation, and storage (CCUS)
Preserved historic blast furnaces
See also
Bibliography
External links
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